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2018 Effects of Zn Concentration (0.5, 1 wt.%) and Heat Treatment on the Microstructure and Corrosion Behavior of Magnesium-Zinc Alloys

Under different heat treatment kinds and conditions T4 (solution treatment) and T6 (aging treatment), whereas the heat treatment is one of an active ways to improve performance. If it is possible to combine the alloying and aging treatment correctly, thus, the performance of magnesium alloys can be more developed. In addition several studies have shown that alloying is a beneficial way to improve the performance of magnesium alloys where refining structures have been widely recognized, enhanced solid solution and enhanced dispersion. [1, 2] and alloys are created in engineering applications by adding a number of different elements such as Al, Zn, Mn, to improve the strength , corrosion resistance and other properties of magnesium. Zinc (Zn) is one of the elements that is used effectively in the alloying of magnesium. In this study the experimental method included the addition of 99.9% pure Mg and Zinc element for the production of magnesium alloys were carried out. Analyzes of the obtained alloys were made at X –Ray Fluorescence (XRF). The materials used in this study were ingots of Mg alloys containing MgxZn (x= 0.5,1, wt.% Zn). Several tests were performed, including microstructure analysis of samples before and after heat treatment including T4 (solution treatment) for the homogenization heat treatment, the temperature of the furnace was chosen as 400 ° C, at this temperature, the material was left for 24 hours and then cooled in water. T6 (aging treatment) was done for the application of aging heat treatment, 2 different hours were selected at 200 ° C (8 and 16hours). After aging, the material was allowed to cool at room temperature. The electrochemical test of corrosion was also done for samples with a diameter of 17 mm and a surface area 2.26 cm2 which exposed to electrolyte. Experiments were performed at room temperature in a glass cell containing 3.5% NaCl solution. Potentiodynamic polarization curves were generated by sweeping the potential from cathodic to anodic direction at a scan rate of 1 mV s−1, starting from -0.5 V up to 0.5 V, versus OCP. Vickers hardness, corrosion behaviors and optical microscope investigations of MgxZn (x= 0.5, 1 wt.% Zn) of magnesium alloys were performed in this study. Microstructure studies have shown that the grain boundaries are larger before heat treatment and grain structures are finer after heat treatment. The grain size of the alloys decreased with the increasing of zinc content. Zinc element enriches along grain boundaries to display a network microstructure for both T4 and T6-treated alloy. The grain refinement effect of a solid solute element can be determined by calculating the grain growth limiting factor (GRF). In the literature [3], the Zn element has a higher GRF than the Al (4,32) and Y (1,70) GRF values of 5,31 GRF, has a growth-limiting effect, which means that the grain-thinning effect is high.

International Symposium on Light Alloys and Composite Materials
UHAKS

Erkan Koç Fozi Mustafa Salem Makhlof

455 247
Subject Area: Chemistry Broadcast Area: International Type: Oral Paper Language: English